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 04.05.2008   Карта сайта     Language По-русски По-английски
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04.05.2008



Locking up radiotoxicity



02 May 2008



International scientists are using computer simulations to give insights into the long-term safety of nuclear waste in deep geological repositories.



powellite structure








Under repository conditions, the lanthanides would regularly alternate with calcium and sodium cations in the solids



Disposing of radiotoxic elements safely is a big challenge, with the concept of storing it in rooms excavated deep within stable, low-permeability rock being one possible solution.  Such a repository would need to be stable for up to a million years into the future, so understanding how the materials would interact with each other over that time is vital.


It is particularly important to retain actinides safely because they have such long radioactive half-lives.  One way this is done is by forming thermodynamically stable solid solutions, where the solids' cations can be substituted by the actinides preventing them from leaching out.  Victor Vinograd at the Institute of Geosciences, Frankfurt, Germany, Dirk Bosbash at the Institute of Nuclear Waste Disposal, Karlsruhe, Germany, and international collaborators have carried out computer simulations to try to understand the behaviour of one such solid solution based on powellite, a naturally occurring mineral, and a lanthanide, which has similar chemical behaviour to the actinides.  


'Such simulations allow us find the conditions under which radionucleotides are stable in the repository system,' explains Vinograd.  The team found that at temperatures typical for repository conditions, the lanthanides would regularly alternate with calcium and sodium cations in the solids.  Vingrad says that the results leave little doubt that at these temperatures, the formation of stable solid solutions is possible only with specific solids that can form the correct cation/actinide ratios.  Next the team hopes to move on to look at chemically more complex waste repository systems in the future, he says.


Madelaine Chapman




Link to journal article



Subsolidus phase relations in Ca2Mo2O8–NaEuMo2O8-powellite solid solution predicted from static lattice energy calculations and Monte Carlo simulations
Victor L. Vinograd, Dirk Bosbach, Björn Winkler and Julian D. Gale, Phys. Chem. Chem. Phys., 2008
DOI: 10.1039/b801912f


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  • Harton Vladislav Vadim  honorary member of ISSC science council

  • Lichtenstain Alexandr Iosif  honorary member of ISSC science council

  • Novikov Dimirtii Leonid  honorary member of ISSC science council

  • Yakushev Mikhail Vasilii  honorary member of ISSC science council

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