Nature Chemistry/ Proton conduction: Hopping along hydrogen bonds - pp432 - 433
Rodolphe Vuilleumier & Daniel Borgis
doi:10.1038/nchem.1365
Proton conduction in both water and other hydrogen-bonded liquids occurs through successive proton transfers along the hydrogen-bond network. But first-principles simulations have revealed that the mechanism by which this occurs in orthophosphoric acid has some unusual features.
|