03.11.2008
РОССИЙСКАЯ АКАДЕМИЯ НАУК

УРАЛЬСКОЕ ОТДЕЛЕНИЕ

ИНСТИТУТ ХИМИИ TBEPДОГО ТЕЛА
   
| | | | |
| | | | | |
 03.11.2008   Карта сайта     Language По-русски По-английски
Новые материалы
Экология
Электротехника и обработка материалов
Медицина
Статистика публикаций


03.11.2008

New nanocluster to boost thin films for semiconductors


University of Oregon, Oregon State discovery speeds production and yields; may lead to greener process
















Graduate student Zachary Mensinger, left, talks with co-authors Lev N. Zakharov, center, and Darren Johnson in Zakharov's lab in the underground Lorry I. Lokey Laboratories at the University of Oregon....

Click here for more information.




Oregon researchers have synthesized an elusive metal-hydroxide compound in sufficient and rapidly produced yields, potentially paving the way for improved precursor inks that could boost semiconductor capabilities for large-area applications.


The key to a "bottom-up" production of possibly the first heterometallic gallium-indium hydroxide nanocluster was the substitution of nitroso-butylamine as an additive in place of nitrosobenzene.


The substitute was identified during a comprehensive screening of potential alternatives by Zachary L. Mensinger, a doctoral student in the lab of University of Oregon chemist Darren W. Johnson. The additive acts to optimize and speed crystallization, allowing for reaction yields up to 95 percent. Comparable compounds traditionally made under caustic conditions often take months or even years to crystallize and result in low yields.


"The benefit is that we can predictably control the ratio of gallium and indium in these structures at molecular levels, which can result in the same control in the fabrication of semiconductor thin films," Johnson said. "We can tailor the properties for specific applications or for different performance levels."


Six University of Oregon and Oregon State University collaborators, working under the umbrella of the Oregon Nanoscience and Microtechnologies Institute (ONAMI), a state signature research center, describe their findings a paper to appear in the German Chemical Society's journal Angewandte Chemie (Applied Chemistry) International. The research, published early online, also was performed under the auspices of a new National Science Foundation-funded Center for Green Materials Chemistry, operated jointly by the two Oregon universities.


"Researchers working in the solid-state materials community are looking at these kinds of nanoclusters as precursors for thin films and other advanced materials, but you typically cannot get them in high enough yields," said Johnson, who also is a member of the UO's Materials Science Institute. "Our synthesis, however, allows for gram-scale quantities."


The results represent a significant breakthrough in the way liquids are produced for semiconductor fabrication, said co-author Douglas A. Keszler, distinguished professor of chemistry at Oregon State and adjunct UO chemistry professor. "We now have new methods for pushing printed inorganic electronics to higher levels of performance within a useful class of materials."


Researchers in Johnson's lab have been experimenting with low-temperature production of a series of such heterometallic nanoclusters, which consist of 13 atoms and contain two different metals in the metal 13 framework, which may prove desirable for long-term applications in solid-state electronics. The nanocluster identified in the paper is labeled a Ga7In6 hydroxide.


"We're starting from a bottom-up approach, in that we can make these with the ratios we desire already built in," Mensinger said. "Using this nitroso compound, we get a higher yield and at a larger scale. I screened several of these compounds to narrow down the best choice. We can also re-use the nitroso compound. It is still present at the end of the reaction, so we can remove it and use it in future reactions."


While the nitroso compound produces usable amounts of nanoclusters for potential semiconductor applications and is reusable in subsequent production, it is toxic, Johnson noted. "It is great because it allowed us to make these clusters that had never been made before, but it is not truly a green-chemistry method," Johnson said. "We're looking at how it works and hope to replace it with a more benign reagent."



###


Co-authors with Mensinger, Johnson and Keszler on the paper were Jason T. Gatlin and Lev N. Zakharov, both of the University of Oregon, and Stephen T. Meyers, a graduate student of Keszler's at OSU.


The National Science Foundation helped support the research through a CAREER award to Johnson and an Integrative Graduate Education and Research Training grant. Additional funding came from the Research Corp. through a 2006 Cottrell Scholar award to Johnson and Army Research Laboratory funds provided through ONAMI.



About the University of Oregon



The University of Oregon is a world-class teaching and research institution and Oregon's flagship public university. The UO is a member of the Association of American Universities (AAU), an organization made up of 62 of the leading public and private research institutions in the United States and Canada. Membership in the AAU is by invitation only. The University of Oregon is one of only two AAU members in the Pacific Northwest.


Sources: Darren Johnson, assistant professor of chemistry, 541-346-1695, dwj@uoregon.edu; Douglas Keszler, distinguished professor of chemistry, Oregon State University, 541-737-6736, Douglas.Keszler@oregonstate.edu


Links: Johnson faculty page: http://www.uoregon.edu/~chem/dwjohnson.html; Keszler faculty page: http://chemistry.oregonstate.edu/keszler.html; UO chemistry department: http://darkwing.uoregon.edu/~chem/; UO Materials Science Institute: http://materialscience.uoregon.edu/


Дизайн и программирование N-Studio 
А Б В Г Д Е Ё Ж З И Й К Л М Н О П Р С Т У Ф Х Ц Ч Ш Щ Ъ Ы Ь Э Ю Я
  • Chen Wev   honorary member of ISSC science council

  • Harton Vladislav Vadim  honorary member of ISSC science council

  • Lichtenstain Alexandr Iosif  honorary member of ISSC science council

  • Novikov Dimirtii Leonid  honorary member of ISSC science council

  • Yakushev Mikhail Vasilii  honorary member of ISSC science council

  • © 2004-2024 ИХТТ УрО РАН
    беременность, мода, красота, здоровье, диеты, женский журнал, здоровье детей, здоровье ребенка, красота и здоровье, жизнь и здоровье, секреты красоты, воспитание ребенка рождение ребенка,пол ребенка,воспитание ребенка,ребенок дошкольного возраста, дети дошкольного возраста,грудной ребенок,обучение ребенка,родить ребенка,загадки для детей,здоровье ребенка,зачатие ребенка,второй ребенок,определение пола ребенка,будущий ребенок медицина, клиники и больницы, болезни, врач, лечение, доктор, наркология, спид, вич, алкоголизм православные знакомства, православный сайт творчeства, православные рассказы, плохие мысли, православные психологи рождение ребенка,пол ребенка,воспитание ребенка,ребенок дошкольного возраста, дети дошкольного возраста,грудной ребенок,обучение ребенка,родить ребенка,загадки для детей,здоровье ребенка,зачатие ребенка,второй ребенок,определение пола ребенка,будущий ребенок