27.11.2010
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27.11.2010


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Inorganica Chimica Acta
Volume 363, Issue 15, 10 December 2010, Pages 4148-4157
Special Volume: Protagonists in Chemistry: Dedication to Professor Achim Müller





Review


The molecular path to inorganic materials – Zinc oxide and beyond





Sebastian PolarzCorresponding Author Contact Information, a, E-mail The Corresponding Author, Carlos Lizandara Pueyoa and Michael Krumma   [Author vitae]






a Department of Chemistry, University Konstanz, 78457 Konstanz, Germany





Received 18 March 2010; 


revised 23 June 2010; 


accepted 28 June 2010. 


Available online 10 July 2010.









Abstract


In the current article, we present a concept for the synthesis of complex nanoscaled materials. The synthetic strategy involves a stepwise assembly of materials starting from special molecular precursors possessing multiple information. Therefore, the article focuses on a strong pervasion of inorganic materials chemistry, solid-state chemistry and molecular chemistry. The concept introduced is finally highlighted by examples from our current research in the field of zinc oxide materials.









Graphical abstract


A concept for the synthesis of complex nanoscaled inorganic materials is presented. It involves the assembly of materials using special molecular precursors. The article focuses on the relation between inorganic materials chemistry, solid-state chemistry and molecular chemistry. The concept is highlighted by examples from the field of zinc oxide materials.









 









































Corresponding Author Contact InformationCorresponding author. Tel.: +49 7531 884415; fax: +49 7531 884406.



Vitae









Image Prof. Polarz was born in Bielefeld/Germany in 1974. He received his Diploma-degree from the University of Bielefeld in 1999 working together with Prof. A. Mueller on polyoxometalate chemistry. For PhD, he moved to the Max-Planck Institute for Colloids in Interfaces where has worked in the group of Prof. M. Antonietti. After a one-year Post-Doc together with Prof. G. A. Ozin/Toronto, Canada Prof. Polarz returned to Germany in 2003 starting his academic career as an Emmy-Noether research group leader first at the Ruhr-University Bochum and then at the Technical University Berlin. In 2007 he received a call to a W-3 professorship for functional inorganic materials at the University of Konstanz. Prof. Polarz research interests involve the areas ’mesoporous materials’, ’precursor chemistry’, ’self-assembly’, ’metal oxide semiconductors’ and ’heterogeneous catalysis’.








Image Carlos Lizandara-Pueyo was born in Barcelona (Spain) in 1982. He received his Diploma in chemistry from the University of Barcelona in 2007. At the same year he went to the University of Konstanz to undertake a doctoral thesis under the supervision of Prof. Dr. Sebastian Polarz. His topic is the synthesis of novel materials by a control over the shape of Zinc Oxide nanoparticles.








Image Michael Krumm was born in Singen Htwl. (Germany) in 1984. He received his Diploma in chemistry from the University of Konstanz in 2009. He then remained in Konstanz to do his doctor’s degree with Prof. Dr. Sebastian Polarz working on new ways to synthesize functional metal-chalkogenid-materials from molecular precursors.



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