24.08.2015

 A superconductor is a material that can conduct electricity without resistance below a superconducting transition temperature, T_c. The highest T_c that has been achieved to date is in the copper oxide system¹: 133 kelvin at ambient pressure² and 164 kelvin at high pressures³. As the nature of superconductivity in these materials is still not fully understood (they are not conventional superconductors), the prospects for achieving still higher transition temperatures by this route are not clear. In contrast, the Bardeen–Cooper–Schrieffer theory of conventional superconductivity gives a guide for achieving high T_c with no theoretical upper bound—all that is needed is a favourable combination of high-frequency phonons, strong electron–phonon coupling, and a high density of states⁴. These conditions can in principle be fulfilled for metallic hydrogen and covalent compounds dominated by hydrogen^{5, 6}, as hydrogen atoms provide the necessary high-frequency phonon modes as well as the strong electron–phonon coupling. Numerous calculations support this idea and have predicted transition temperatures in the range 50–235 kelvin for many hydrides⁷, but only a moderate T_c of 17 kelvin has been observed experimentally⁸. Here we investigate sulfur hydride⁹, where a T_c of 80 kelvin has been predicted¹⁰. We find that this system transforms to a metal at a pressure of approximately 90 gigapascals. On cooling, we see signatures of superconductivity: a sharp drop of the resistivity to zero and a decrease of the transition temperature with magnetic field, with magnetic susceptibility measurements confirming a T_c of 203 kelvin. Moreover, a pronounced isotope shift of T_c in sulfur deuteride is suggestive of an electron–phonon mechanism of superconductivity that is consistent with the Bardeen–Cooper–Schrieffer scenario. We argue that the phase responsible for high-T_c superconductivity in this system is likely to be H₃S, formed from H₂S by decomposition under pressure. These findings raise hope for the prospects for achieving room-temperature superconductivity in other hydrogen-based materials.

• Лаборатория оксидных систем
• Лаборатория нестехиометрических соединений
• Лаборатория гетерогенных процессов
• Лаборатория неорганического синтеза
• Лаборатория химии соединений редкоземельных элементов
• Лаборатория структурного и фазового анализа
• Лаборатория физико-химических методов анализа
• Лаборатория квантовой химии и спектроскопии им. профессора А.Л. Ивановского
• Лаборатория физико-химии дисперсных систем
• Лаборатория перспективных функциональных материалов для химических источников тока
• Лаборатория ионики твёрдого тела
• Группа патентно-конъюнктурных исследований